The ultimate trickster, Loki’s intelligence, wit, and snarky smile consistently fools his brother Thor and most of the Avengers for that matter. In The Avengers movie, Loki develops a plan to subjugate humanity using an army of the Chitauri. But first, he willfully gets captured by Captain America and Iron Man to infiltrate their flying aircraft carrier. Using the Hulk and a brainwashed Hawkeye, Loki breaks up the Avengers to keep them distracted. His cunning almost brings him to his goal, but the Avengers put a stop to it just in time.