Brad Pitt. Brad Pitt has become one of the best-known actors in Hollywood over the past few decades. He has filmed his own fair share of love scenes, while dating a number of different actresses. It seems that Brad’s entire outlook on life changed when he married Angelina Jolie. Since Brad then declared that he wouldn’t be part of any more make-out sessions on-screen out of respect for his wife. While on the set of The Curious Case of Benjamin Button, Brad initially refused to kiss the stunning redhead who had been chosen specifically for that scene. The director David Fincher was stunned, and many of Brad’s fans assumed that Angelina was the reason Brad hadn’t wanted to, since he didn’t want to cause any issues at home with his wife. Brad obviously decided to kiss the girl in the end, but these were the first signs that his marriage to Jolie was beginning to unravel.