Kaifeng took the lead with 1 million people by 1000.
Located near China's Grand Canal, Kaifeng was the capital of the Song dynasty.
It was the most industrialized city in the world, with vast iron works and shops, bars, and theaters filling every corner.
As the city ran low on wood to burn, Kaifeng discovered the potential of coal and tapped a major nearby deposit. Twenty new coal markets opened in the city from 1102 to 1106.