The couple got together after the filming of Mr. & Mrs. Smith in 2005, and eventually became one of the most prominent couples in Hollywood. The beginning of their relationship was a bit harsh, since Brad Pitt had been together with Jennifer Aniston for several years. The actors got married on August 23, 2014, but in 2016 Angelina filed for divorce, claiming they had different opinions regarding the education of their 6 children.